Epoxy resin composites reinforced with different weight fractions of TiO2 micro-particles 0.2μm in size (1%, 5%, 10%, 15%wt) and of TiO2 nano-particles 21nm in size (0.5%, 1%, 3%wt) were manufactured. The quasi-static mechanical properties of both nano-composites and micro-composites were investigated and compared through tensile testing. The experimental results were predicted and the degree of matrix-particle adhesion and particle dispersion were evaluated, by the Property Prediction Model (PPM) developed by the first author. The composites were also subjected to creep-recovery tests as well as to relaxation tests in order to investigate their viscoelastic behaviour. The experiments were carried out at different filler-weight fractions and loading conditions. Non-linear viscoelastic behaviour was observed in all cases and appropriate models were applied in order to describe, and/or predict the viscoelastic behaviour of all materials tested. A fair agreement between experimental results and theoretical predictions was observed for both viscoelastic and static results.
Journal Information
Vol. 28. Issue 2.
Pages 138-146 (July - December 2016)
Vol. 28. Issue 2.
Pages 138-146 (July - December 2016)
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Viscoelastic behaviour and modelling of nano and micro TiO2 powder-epoxy resin composites
Visits
1951
G.C. Papanicolaou
, L.C Kontaxis, A.E. Manara
Corresponding author
The Composite Materials Group, Department of Mechanical and Aeronautics Engineering, University of Patras, Patras, GR-26500, Greece
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Abstract
Keywords:
viscoelastic
nano
micro
TiO2
titania
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References
[1]
A. Chatterjee, M.S. Islam.
Mater. Sci. Eng., A, 487 (2008), pp. 574
[2]
C. Chen, R.S. Justice, D.W. Schaefer, J.W. Baur.
Polymer, 49 (2008), pp. 3805
[3]
J. Baller, N. Becker, M. Ziehmer, M. Thomassey, B. Zielinski, U. Muller, R. Sanctuary.
Polymer, 50 (2009), pp. 3211
[4]
R. Zhao, W. Luo.
Mater. Sci. Eng., A, 483–484 (2008), pp. 313
[5]
Y. Zheng, Y. Zheng, R. Ning.
Mater. Lett., 57 (2003), pp. 2940
[6]
V. Kostopoulos, A. Baltopoulos, P. Karapappas, A. Vavouliotis, A. Paipetis.
Compos. Sci. Technol., 70 (2010), pp. 553
[7]
J. Leidner, R.T. Woodhams.
J. Appl. Polym. Sci., 18 (1974), pp. 1639
[8]
A.N. Gent, B. Park.
J. Mater. Sci., 19 (1984), pp. 1947
[9]
K.C. Radford.
J. Mater. Sci., 6 (1971), pp. 1286
[10]
Y. Nakamura, M. Yamaguchi, M. Okubo, T. Matsumoto.
J. Appl. Polym. Sci., 44 (1992), pp. 151
[11]
N. Suprapakorn, S.S. Dhamrongvaraporn, H. Ishida.
Polym. Compos., 19 (1998), pp. 26
[12]
Z.K. Zhu, Y. Yang, J. Yin, Z.N. Qi.
J. Appl. Polym. Sci., 73 (1999), pp. 2977
[13]
J. Cho, M.S. Joshi, C.T. Sun.
Compos. Sci. Technol., 66 (2006), pp. 1941
[14]
X.L. Ji, J.K. Jing, B.Z. Jiang.
Polym. Eng. Sci., 42 (2002), pp. 983
[15]
J. Douce, J.P. Boilot, J. Biteau, L. Scodellaro, A. Jimenez.
Thin Solid Films, 466 (2004), pp. 114
[16]
S. Mishra, S.H. Sonawane, R.P. Singh.
J. Polym. Sci., Part B: Polym. Phys., 43 (2005), pp. 107
[17]
S.-Y. Fu, X.-Q. Feng, L. Bernd, Y.-W. Mai.
Composites.
Part B, 39 (2008), pp. 933
[18]
L. Cano, J. Gutierrez, A.E. Di Mauro, M.L. Curri, A. Tercjak.
Electrochim. Acta., 184 (2015), pp. 8
[19]
Y. Li, J. Luo, X. Hu, X. Wang, j> Liang, K. Yu.
J. Alloys Compd., 651 (2015), pp. 685
[20]
A.I. Kociubczyk, M.L. Vera, C.E. Schvezov, E. Heredia, A.E. Ares.
Procedia Mater. Sci., 8 (2015), pp. 351
[21]
C.D. Madhusoodana, S.P. Manjunath, R.N. Das.
Procedia Eng., 44 (2012), pp. 939
[22]
T. Plecenik, M. Mosko, A.A. Haidry, P. Durina, M. Truchly, B. Grancic, M. Gregor, T. Roch, L. Satrapinskyy, A. Moskova, M. Mikula, P. Kus, A. Plecenik.
Sens. Actuators, B., 207 (2015), pp. 351
[23]
K. Choi, W. Lee.
Ch. Lim, Mater. Lett., 158 (2015), pp. 36
[24]
K.G. Binu, B.S. Shenoy, D.S. Rao, R. Pai.
Procedia Mater. Sci., 6 (2014), pp. 1051
[25]
A. Purniawan, P.J. French, G. Pandraud, P.M. Sarro.
Procedia Eng., 5 (2010), pp. 1131
[26]
C.B. Ng, L.S. Schadler, R.W. Siegel.
Nanostruct. Mater., 12 (1999), pp. 507
[27]
H.A. Al-Turaif.
Prog. Org. Coat, 69 (2010), pp. 241
[28]
M. Kosmulski.
Surface charging and points of zero charge.
CRC Press, (2009),
[29]
G.C. Papanicolaou, A.F. Koutsomitopoulou, A. Sfakianakis.
J. Appl. Polym. Sci., 124 (2011), pp. 67
[30]
G.C. Papanicolaou, L.C. Kontaxis, A.F. Koutsomitopoulou, S.P. Zaoutsos.
J. Appl. Polym. Sci., 132 (2015), pp. 41697
[31]
F. Rabbi, PhD thesis, (2014) Retrieved from http://scholarcommons.sc.edu/etd/2868
[32]
G.C. Papanicolaou, T.V. Kosmidou, A.S. Vatalis, C.G. Delides.
J. Appl. Polym. Sci., 99 (2006), pp. 1328
[33]
G.C. Papanicolaou, A.G. Xepapadaki, G.A. Angelakopoulos.
J. Appl. Polym. Sci., 126 (2012), pp. 559
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