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Inicio Ciência & Tecnologia dos Materiais Application in chromium (VI) removal of natural and dried cactus
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Vol. 29. Issue 3.
Pages 145-152 (September - December 2017)
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Vol. 29. Issue 3.
Pages 145-152 (September - December 2017)
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Application in chromium (VI) removal of natural and dried cactus
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F. Sakr
Corresponding author
sakrfatima@gmail.com

Corresponding author.
, A. Sennaoui, M. Dinne, S. Alahiane, I. Bakas, M. Belmoden, A. Assabbane
Laboratory of Electrochemistry, Catalysis and Environment, Team Catalysis and Environment, Faculty of Science, Ibn Zohr University, Agadir, Morocco
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Abstract

This research presents two type of cactus (Opuntia ficus-indica) (natural cactus (NC) and dried cactus (DC)) as a biological adsorbent, evaluated for the effectiveness of hexavalent chromium Cr(VI) removal from artificially contaminated aqueous solutions. The characterization of the biosorbents were made using different techniques such as X-ray Fluorescence (XRF), Fourier transform infrared (FTIR) and Scanning Electron Microscope (SEM) to better understand the adsorption mechanism-property relationship. Adsorption kinetics showed that the adsorption behavior followed the pseudo-second-order kinetic model. The adsorption isotherms fitted by the Langmuir model showed that the highest Cr(VI) adsorption capacities using natural cactus and dried cactus are 21.19 and 2.63mg/g respectively. Additionally, various physiochemical parameters such as contact time, adsorbent dosage, pH and temperature were investigated in a batch-adsorption technique. The results illustrated that the cactus have significant potential as economic, safe and effective adsorbent materials for the Cr(VI) adsorption from the aqueous solution.

Keywords:
Adsorption
natural cactus
dried cactus
hexavalent chromium
biosorbent
isotherms
kinetic
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References
[1]
A.K. Shanker, C. Cervantes, H. Loza-Tavera, S. Avudainayagam.
Environ. Int, 31 (2005), pp. 739
[2]
K.J. Cronje, K. Chetty, M. Carsky, J.N. Sahu, B.C. Meikap.
Desalination, 275 (2011), pp. 276
[3]
B. Saha, C. Orvig.
Coord. Chem. Rev, 254 (2010), pp. 2959
[4]
Z. Zainul Akmar, S. Marlini, M. Nurfadilah, A. Wan Azlina.
Desalination, 244 (2009), pp. 109
[5]
R.Y. Taj, S. Renganathan, N. Partha, G. Baskar, M. Velan.
Clean - Soil, Air, Water, 37 (2009), pp. 787
[6]
D. Sarkar, S.K. Das, P. Mukherjee, A. Bandyopadhyay.
Clean - Soil, Air.
Water, 38 (2010), pp. 764
[7]
P.S. Kumar, S. Ramalingam, R.V. Abhinaya, S.D. Kirupha, A. Murugesan, S. Sivanesan.
Clean - Soil Air Water, 40 (2012), pp. 188
[8]
S. Chen, Q. Yue, B. Gao, Q. Li, X. Xu, K. Fu.
Bioresour. Technol, 113 (2012), pp. 114
[9]
K. Mohanty, M. Jha, B.C. Meikap, M.N. Biswas.
Chem. Eng. J, 117 (2006), pp. 71
[10]
J.N. Sahu, J. Acharya, B.C. Meikap.
J. Hazard. Mater, 172 (2009), pp. 818
[11]
J. Rodier, B. Legube, N. Merlet.
Coll..
L’analyse de l’eau, 9ème edition, Dunod, (2009),
[12]
F.T. Li, H. Yang, Y. Zhao, R. Xu.
Chinese Chem. Lett, 18 (2007), pp. 325
[13]
N.V. Farinella, G.D. Matos, M.A.Z. Arruda.
Bioresour. Technol, 98 (2007), pp. 1940
[14]
J.V. Ibarra, R. Moliner.
J. Anal. Appl. Pyrolysis, 20 (1991), pp. 171
[15]
N. Barka, K. Ouzaouit, M. Abdennouri, M. Makhfouk.
J. Taiwan Inst. Chem. Eng, 44 (2013), pp. 52
[16]
D. Park, S.R. Lim, Y.S. Yun, J.M. Park.
Bioresour. Technol, 99 (2008), pp. 8810
[17]
B. Mahjoub, I. Fkih, M.C. Nacibi. Élimination du chrome hexavalent des solutions aqueuses par adsorption sur feuilles brute de de Posidonia oceanica (L.): cinétiques, équilibres et modélisation, Déchets - Revue francophone d’écologie industrielle, Sousse, 2009, pp. 19-26.
[18]
M.J. Sarre, M. Mazet.
Rev. Sci. Eau, 1 (1988), pp. 55
[19]
N. Daneshvar, D. Salari, S. Aber.
J. Hazard. Mater, B94 (2002), pp. 49
[20]
A. Asfaram, M. Ghaedi, G.R. Ghezelbash.
RSC Adv, 6 (2016), pp. 235999
[21]
M.C. Ncibi, B. Mahjoub, M. Seffen.
J. Hazard. Mater, B139 (2007), pp. 280
[22]
O. Samson, C. Owalude, Adedibu.
Tella, J. Basic & Appl. Sci, 5 (2016), pp. 377
[23]
B. Song, G. Zeng, J. Gong, P. Zhang, J. Deng, C. Deng, J. Yan, P. Xu, C. Lai, C. Zhang, M. Cheng.
Chemosphere, 172 (2017), pp. 449
[24]
C. Kannan, K. Muthuraja, M.R. Devi.
J. Hazard. Mater, 10 (2013), pp. 244
[25]
K. Selvi, S. Pattabhi, K. Kadirvelu.
Bioresour. Technol, 80 (2001), pp. 87
[26]
D.C. Sharma, C.F. Forster.
Bioresour. Technol, 49 (1994), pp. 31
[27]
S. Mor, K. Ravindra, N.R. Bishnoi.
Bioresour. Technol, 98 (2007), pp. 954
[28]
S.S. Baral, S.N. Das, P. Rath, G.R. Chaudhury.
Bioch. Eng. J, 34 (2007), pp. 69
[29]
M. Dakiky, M. Khamis, A. Manassra.
M. Mer’eb, Adv. Environ. Res, 6 (2002), pp. 533
[30]
N. Zhu, T. Yan, J. Qiao, H. Cao.
Chemosphere, 164 (2016), pp. 32
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